CEC 金属团簇催化

目前工作组成员：崔超男、程然、袁江陆、Aamir Shehzad 

（Cecil）

金属团簇催化剂由于其多位点协同效应与可调节的稳定性与催化活性，且兼有电子传输助剂和电子缓冲剂的功能、金属活性位配位不饱和特性、团簇-基体共促效应，是设计开发新型催化剂的理想模型。该方向主要结合电化学反应，理论结合实验地开展团簇负载电极的电催化氮循环反应研究。

团簇软沉积与电化学反应系统（SD-CEC）

 

References:

[1] Zhixun Luo; Aamir Shehzad, Advances in naked metal clusters for catalysis. ChemPhysChem 2024, e202300715 (Invited review). 

[2] R. Cheng;  C. Cui; Z. Luo, Catalysis of dinitrogen activation and reduction by a single Fe13 cluster and its doped systems. Phys. Chem. Chem. Phys. 2023, 25 (2), 1196–1204

[3] Chaonan Cui;  Hongchao Zhang;  Ran Cheng;  Benben Huang; Zhixun Luo, On the Nature of Three-Atom Metal Cluster Catalysis for N2 Reduction to Ammonia. ACS Catal. 2022, 14964–14975. 

[4] C. Cui, Y. Jia, H. Zhang, L. Geng, Z. Luo, Plasma-Assisted Chain Reactions of Rh3+ Clusters with Dinitrogen: N identical withN Bond Dissociation. J. Phys. Chem. Lett.,  2020, 11, 8222-8230.

[5] Chaonan Cui, Zhixun Luo*, Jiannian Yao, Enhanced Catalysis of Pt3 Clusters Supported on Graphene for N-H Bond Dissociation, CCS Chem. 2019, 1, 215-225.