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骆智训 研究员

     

骆智训，研究员，博士生导师，中国科学院化学研究所分子动态稳态结构国家重点实验室。2009年于化学所获得博士学位（导师:姚建年院士），同年7月赴美国宾夕法尼亚州立大学从事博士后研究工作（合作导师:A.W.Castleman,Jr.院士）。2013年11月回国工作，任化学所研究员，2015年入选海外高层次人才引进青年项目，2017年获国家自然科学基金委优秀青年基金资助。中国科学院大学兼职教授（主讲本科生《高等无机化学导论》），《中国化学快报》编委、《结构化学》青年编委，曾获中国科学院杰出科技成就奖（完成者之一）。

主要以金属团簇和分子聚集体为研究对象，致力于金属表面化学反应的微观机制研究，围绕金属团簇和超原子的制备/检测、稳定性/反应性与功能化相关科学问题，设计研制了多套创新性的大型仪器系统，并在此基础上实现了中性/正/负电荷的1-40个原子的多种金属团簇的制备与反应表征技术联用，建立了深紫外/红外离子化质谱光谱技术（DUV+IR）和基于富压层流反应的自定义三重四极杆质谱与软沉积技术（MIFT-TQMS）。系统考察了尺寸依赖的金属团簇稳定性与反应性，发展了金属有机簇合物气相合成及其光谱学研究新方法，提出了"狭义和广义超原子" 概念（Special and General Superatoms），把气相金属团簇与配体保护金属团簇关联起来。提出团簇基因与超原子化学研究框架，初步构筑了三维元素周期表及在此基础上的超原子团簇基因新材料。理论结合实验探究了析氢和固氮反应的三原子金属团簇催化机制。

发表第一/通讯作者论文 160 余篇，包括Sci. Adv. 1 篇、J. Am. Chem. Soc. 5 篇，Natl. Sci. Rev. 2 篇，CCS Chem. 4 篇，Sci. Bull.、Angew. Chem. Int. Ed.、Chem. Sci.、ACS Catal. 各一篇，Commun. Chem. 3 篇，Rev. Sci. Instrum. 3 篇，J. Phys. Chem. Lett. 8 篇，PCCP/JPC/CPC 40余篇；应邀在 Acc. Chem. Res.、Chem. Rev. 和 Coord. Chem. Rev. 撰写重要综述 5 篇；合作论著 3 章，专著《Metal Clusters and Their Reactivity》在 Springer 出版。
主要学习与作经历：
2013.11—至今       中国科学院化学研究所,  研究员     
2009.7—2013.7     Penn. State University 博士后& 助教，团簇物理化学 (PI: A.W. Castleman,Jr.院士)
2006.9—2009.6     中国科学院化学研究所，博士学位，物理化学 (光化学，导师：姚建年院士)
2003.9—2006.6     首都师范大学，硕士学位，物理学 （光学专业，导师：方炎教授）
1998.9—2002.6     三峡大学，学士学位，物理学（教育类）

 

代表性文章：

  1. Zhixun Luo*,Castleman, A. W.,Jr.* Special and General Superatoms. Acc. Chem. Res. 2014, 47, 2931-2940.
  2. Zhixun Luo*, A. W. Castleman, Jr.*, and Shiv N. Khanna*. Reactivity of Metal Clusters. Chem. Rev., 2016, 116, 14456−14492
  3. Yuhan Jia, Zhixun Luo*, Thirteen-atom metal clusters for genetic materials, Coord. Chem. Rev., 2019, 400, 213053.
  4. Baoqi Yin and Zhixun Luo*, Coinage Metal Clusters: From Superatom Chemistry to Genetic Materials, Coord. Chem. Rev., 2021, 429, 213643.
  5. Zhixun Luo*, Shiquan Lin. Advances in Cluster Superatoms for a 3d Periodic Table of Elements, Coord. Chem. Rev. 2024, 500, 215505.
  6. Yuhan Jia;  Cong-Qiao Xu;  Chaonan Cui;  Lijun Geng;  Hanyu Zhang;  Yang-Yang Zhang;  Shiquan Lin;  Jiannian Yao;  Zhixun Luo*; Jun Li*, Rh19−: A high-spin super-octahedron cluster. Sci. Adv. 2023, 9, eadi0214. 
  7. Benben Huang;  Hanyu Zhang;  Wen Gan;  Mengzhou Yang;  Zhixun Luo*; Jiannian Yao, Nb12+——Niobespherene: a full-metal hollow cage cluster with superatomic stability and resistant to CO attack. Natl. Sci. Rev. 2023, 10, nwac197.  
  8. Lijun Geng, Mouyi Weng, Cong-Qiao Xu, Hanyu Zhang, Chaonan Cui, Haiming Wu, Xin Chen, Mingyu Hu, Hai Lin, Zhen-Dong Sun, Xi Wang, Han-Shi Hu, Jun Li, Jiaxin Zheng, Zhixun Luo*, Feng Pan*, Jiannian Yao*, Co13O8—Metalloxocubes: A new class of perovskite-like neutral clusters with cubic aromaticity, Natl. Sci. Rev. 2021, 8(1), naaa201.
  9. Chaonan Cui;  Hanyu Zhang;  Yuming Gu;  Lijun Geng;  Yuhan Jia;  Shiquan Lin;  Jing Ma*; Zhixun Luo*, Tailoring Titanium Carbide Clusters for New Materials: from Met-Cars to Carbon-Doped Superatoms. J. Am. Chem. Soc. 2024,146 (13), 9302-9310.
  10. L. Geng;  T. Sengupta;  X. Li;  C. Cui;  S. Lin;  X. L. Xu;  A. C. Reber;  S. N. Khanna;  W. J. Zheng; Zhixun Luo*, Unusually High-Spin Fe12C12- Metallo-Carbohedrene Clusters. J. Am. Chem. Soc., 2023, 145 (49), 26908–26914. 
  11. Zhixun Luo; Grover, C. J.; Reber, A. C.; Khanna, S. N.*; Castleman, A. W., Jr*: Probing the Magic Numbers of Aluminum–Magnesium Cluster Anions and Their Reactivity toward Oxygen. J. Am. Chem. Soc. 2013, 135, 4307-4313.
  12. Zhixun Luo, Gamboa, G. U.; Smith, J. C.; Reber, A. C.; Reveles, J. U.; Khanna, S. N.*; Castleman, A. W., Jr.*: Spin Accommodation and Reactivity of Silver Clusters with Oxygen: The Enhanced Stability of Ag13-. J. Am. Chem. Soc. 2012, 134, 18973-18978.
  13. Zhixun Luo;Cheng, X.; Luo, Y.; Loo, B. H.; Peng, A.; Yao, J. N.*: Photo-Assisted Magnetization of Fullerene C60 with Magnetic-Field Trapped Raman Scattering.J. Am. Chem. Soc. 2012, 134, 1130-1135.
  14. Lijun Geng;  Chaonan Cui;  Baoqi Yin;  Hanyu Zhang;  Yuhan Jia; Zhixun Luo*, Co12C12-——metallo-carbospherenes: a new class of magic clusters for hydrogen storage. Sci. Bull. 2022, 67 (22), 2280-2284.
  15. L. Geng;  P. Wang;  S. Lin;  R. Shi;  J. Zhao; Zhixun Luo*, On the nature of Con±/0 clusters reacting with water and oxygen. Commun. Chem. 2024, 7 (1), 68.  
  16. Lijun Geng;  Xiaohu Yu; Zhixun Luo*, A stable and strongly ferromagnetic Fe17O10– cluster with an accordion-like structure. Commun. Chem. 2023, 6 (1), 149.  
  17. Hanyu Zhang, Haiming Wu, Yuhan Jia, Baoqi Yin, Lijun Geng, Zhixun Luo* and Klavs Hansen. The Reactivity of Cationic Vanadium Clusters with Water: Hy-drogen Release from Single H2O Molecule on Vn + (3 ≤ n ≤ 30), Commun. Chem., 2020, COMMSCHEM-20-0181C.
  18. Chaonan Cui;  Yuhan Jia;  Hanyu Zhang;  Lijun Geng; Zhixun Luo*, Plasma-assisted Dinitrogen Activation via Dual Platinum Cluster Catalysis: A Strategy for Ammonia Synthesis under Mild Conditions. CCS Chem. 2022, 1, 1-25. 
  19. Baoqi Yin;  Qiuying Du;  Lijun Geng;  Hanyu Zhang;  Zhixun Luo*;  Si Zhou*; Jijun Zhao, Superatomic Signature and Reactivity of Silver Clusters with Oxygen: Double Magic Ag17– with Geometric and Electronic Shell Closure. CCS Chem. 2021, 3, 1–13.
  20. Hanyu Zhang, Arthur C. Reber, Lijun Geng, Daniel Rabayda, Haiming Wu, Zhixun Luo*, Jiannian Yao, and Shiv N. Khanna*, Formation of Al+(C6H6)13: The Origin of Magic Number in Metal-benzene Clusters Determined by the Nature of the Core, CCS Chem. 2019, 1, 571-581.
  21. Chaonan Cui, Zhixun Luo*, Jiannian Yao, Enhanced Catalysis of Pt3 Clusters Supported on Graphene for N-H Bond Dissociation, CCS Chem. 2019, 1, 215-225.
  22. Zhixun Luo, Liu, Y.; Kang, L.; Wang, Y.; Fu, H.; Ma, Y.; Yao, J. N.*; Loo, B. H.: Controllable Nanonet Assembly Utilizing a Pressure-Difference Method Based on Anodic Aluminum Oxide Templates. Angew. Chem. Int. Ed. 2008, 47, 8905 - 8908.
  23. Zhixun Luo*, Arthur C. Reber, Meiye Jia, William H. Blades, Shiv N. Khanna* and A. W. Castleman. Jr.*. What determines if a ligand activates or passivates a superatom cluster?. Chem. Sci., 2016, 7，3067-3074.
  24. Chaonan Cui;  Hongchao Zhang;  Ran Cheng;  Benben Huang; Zhixun Luo*, On the Nature of Three-Atom Metal Cluster Catalysis for N2 Reduction to Ammonia. ACS Catal. 2022, 14964-14975.  
  25. Haiming Wu;  Mengzhou Yang;  Benben Huang;  Wen Gan; Zhixun Luo*, Ligand Accommodation Causes Altered Reactivity of Silver Clusters with Iodomethane: Superatomic Stability of Ag9I2+ in Mimicking XeF2. Sci. China Chem. 2022, 65, 1594-1600.
  26. Haiming Wu; Zhixun Luo*, Chlorine-Passivated Superatom Al37 Clusters for Nonlinear Optics. Sci. China Chem. 2018, 61, 1619–1623.
  27. Chengqian Yuan;  Pan An;  Jing Chen;  Zhixun Luo*; Jiannian Yao*, Unraveling weak interactions in aniline-pyrrole dimer clusters. Sci. China Chem. 2016, 59 (10), 1270-1276. 
  28. L. Geng; Z. Luo, Magnetic Metal Clusters and Superatoms. J. Phys. Chem. Lett. 2024, 1856-1865.  Doi:10.1021/acs.jpclett.3c03637.
  29. B. Huang;  H. Zhang;  L. Geng; Zhixun Luo*, An Open-Shell Superatom Cluster Ta10- with Enhanced Stability by United d-d pi Bonds and d-Orbital Superatomic States. J. Phys. Chem. Lett. 2022, 9711-9717. 
  30. Y. Jia;  J. Li;  M. Huang;  L. Geng;  H. Zhang;  S. B. Cheng*;  Y. Yi; Zhixun Luo*, Ladder Oxygenation of Group VIII Metal Clusters and the Formation of Metalloxocubes M13O8+. J. Phys. Chem. Lett. 2022, 13, 733-739.  
  31. Yuhan Jia;  Xinlei Yu;  Hanyu Zhang;  Longjiu Cheng*; Zhixun Luo*, Tetrahedral Pt10– Cluster with Unique Beta Aromaticity and Superatomic Feature in Mimicking Methane. J. Phys. Chem.Lett. 2021, 5115-5122.
  32. Hanyu Zhang;  Mingzheng Zhang;  Yuhan Jia;  Lijun Geng;  Baoqi Yin;  Shunning Li;  Zhixun Luo*; Feng Pan*, Vanadium Cluster Neutrals Reacting with Water: Superatomic Features and Hydrogen Evolution in a Fishing Mode. J. Phys. Chem.Lett. 2021, 12, 1593-1600.
  33. C. Cui, Y. Jia, H. Zhang, L. Geng, Zhixun Luo*, Plasma-Assisted Chain Reactions of Rh3+ Clusters with Dinitrogen: N identical withN Bond Dissociation. J. Phys. Chem. Lett., 2020, 11, 8222-8230.
  34. B. Yin, Q. Du, L. Geng, H. Zhang, Zhixun Luo*, S. Zhou*and J. Zhao, Anionic Copper Clusters Reacting with NO: An Open-Shell Superatom Cu18, J. Phys. Chem. Lett., 2020, 11, 5807-5814.
  35. Zhixun Luo, Smith, J. C.; Woodward, W. H.; Castleman, A. W., Jr.*: Reactivity of Aluminum Clusters with Water and Alcohols: Competition and Catalysis? J. Phys. Chem. Lett. 2012, 3, 3818-3821.
  36. D. Ma;  X. Lei;  C. Cui;  Q. Yi; Z. Luo*, Hydrogen Evolution Reactions of Hydrocarbons and Hydroborons Promoted by Superatomic Nbn- Clusters. J. Phys. Chem. Lett. 2024, 9888-9893.  Doi:10.1021/acs.jpclett.4c02120.
  37. C. Cui;  Y. Jia;  S. Lin;  L. Geng; Z. Luo*, The Reactivity of Ptn+ Clusters With N2O Facilitated by Dual Lewis-Acid Sites. Small 2024, 1, e2404638.  Doi:10.1002/smll.202404638.

合作论著/专著：

  1. Zhixun Luo and Shiv Khanna, <<Metal Clusters and Their Reactivity>>, 2021 Springer (ISBN 978-981-15-9703-9). https://www.springer.com/in/book/9789811597039 
  2. Zhixun Luo, Book Chapter 1：Deep Ultraviolet Single-Photon Ionization Mass Spectrometry. In 《Mass Spectrometry》 (Ed.: M. Aliofkhazraei), InTech, 2017. (ISBN 978-953-51-5245-3).
  3. Zhixun Luo*, Jiannian Yao. Book Chapter 2：Raman Investigations of Atmoic/Molecular Clusters & Aggregates. in《Raman Spectroscpy and Applications》edited by Khan Maaz, 2017, (ISBN 978-953-51-2908-0), pp31-59.

仪器研制：

  1. Benben Huang, Haiming Wu, Mengzhou Yang, Zhixun Luo*, An integrated instrument of a tandem quadrupole mass spectrometer for cluster reaction and soft-landing deposition  Rev. Sci. Instrum. 2022, 93 (11).  Doi:10.1063/5.0112401..
  2. Hanyu Zhang, Haiming Wu, Yuhan Jia, Lijun Geng, Zhixun Luo*, Hongbing Fu and Jiannian Yao, An integrated instrument of DUV-IR photoionization mass spectrometry and spectroscopy for neutral clusters. Rev. Sci. Instrum. 2019, 90 (7), 073101.
  3. Chengqian Yuan, Xianhu Liu, Chenghui Zeng, Hanyu Zhang,Meiye Jia,Yishi Wu, Zhixun Luo*,Hongbing Fu*,and Jiannian Yao*. All-solid-state deep ultraviolet laser for single-photon ionization mass spectrometry. Rev. Sci. Instrum., 2016, 87, 024102.
  4. Hanyu Zhang;  Lijun Geng;  Yuhan Jia;  Xin Lei; Zhixun Luo*, A 45-degree ion-extraction photoelectron velocity map imaging apparatus coupled to the DUV-IR mass spectrometry and spectroscopy instrument. Int. J. Mass Spectrom. 2022.  Doi:10.1016/j.ijms.2022.116932.
  5. Zhixun Luo;  W. H. Woodward;  J. C. Smith; A. W. Castleman, Growth kinetics of Al clusters in the gas phase produced by a magnetron-sputtering source. Int. J. Mass Spectrom. 2012, 309, 176-181.  Doi:DOI 10.1016/j.ijms.2011.09.016.

专利：

  1. 骆智训; 黄奔奔; 杨梦周; 吴海铭. 一种基于磁控溅射的团簇高效制备与尺寸可调的团簇束源系统 （2019-05-17, 中国, CN201910413543.9）
  2. 骆智训; 杨梦周; 黄奔奔; 崔超男;一种逆压梯度传输的离子透镜系统，（2019-12-12，中国, 201911273046.X）
  3. 骆智训; 黄奔奔; 杨梦周. 一种可插入式气相团簇软沉积装置和方法 (2019-12-12，中国, 2019112734963.9)
  4. 骆智训; 殷保祺; 吴海铭; 郭梦迪. 一种气相团簇反应装置、反应系统与方法 (2020-7-1, 中国, 202010625704.3)
  5. 骆智训; 崔超男; 贾钰涵. 一种等离子体辅助的金属团簇催化氮气活化解离的方法 (2020-9-14, 中国, 202010959466.X)
  6. 张义; 付红兵; 吴义室; 骆智训. 一种基于双受激发射竞争实现的超快光开关及其制备方法(2017-04-18, 中国, CN201710252225.X.)
  7. 姚建年; 骆智训. 一种制备有机网膜的方法 (2008-11-26, 其他国家, CN200810104616.8.)