金属团簇结构化学与反应性研究 金属团簇结构化学与反应性研究

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金属团簇结构化学与反应性研究

工作组成员：耿丽君、林世泉

 

在飞行时间质谱（TOF-MS）基础上，使用我国自主研发的深紫外（DUV）全固态激光器，结合宽调谐红外（IR）激光，能够同时而且准确地测试物质元素组成与化学结构，探究团簇物种的反应活性。

深紫外/红外离子化质谱光谱仪 DUV+IR

 

References

  1. Yuhan Jia;  Cong-Qiao Xu;  Chaonan Cui;  Lijun Geng;  Hanyu Zhang;  Yang-Yang Zhang;  Shiquan Lin;  Jiannian Yao;  Zhixun Luo; Jun Li, Rh19−: A high-spin super-octahedron cluster. Sci. Adv. 2023, 9 (33), eadi0214. 
  2. Chaonan Cui;  Hanyu Zhang;  Yuming Gu;  Lijun Geng;  Yuhan Jia;  Shiquan Lin;  Jing Ma; Zhixun Luo, Tailoring Titanium Carbide Clusters for New Materials: from Met-Cars to Carbon-Doped Superatoms. J. Am. Chem. Soc. 2024, 10.1021/jacs.4c01068.
  3. Lijun Geng;  Turbasu Sengupta;  Xilong Li;  Chaonan Cui;  Shiquan Lin;  Xi-Ling Xu;  Arthur C. Reber;  Shiv N. Khanna;  Wei-Jun Zheng; Zhixun Luo, Unusually High-Spin Fe12C12 Metallo-Carbohedrene Clusters. J. Am. Chem. Soc. 2023, 145 (49), 26908–26914.
  4. Hanyu Zhang;  Lijun Geng;  Yuhan Jia;  Xin Lei; Zhixun Luo*, A 45-degree ion-extraction photoelectron velocity map imaging apparatus coupled to the DUV-IR mass spectrometry and spectroscopy instrument. Int. J. Mass Spectrom. 2022.  Doi:10.1016/j.ijms.2022.116932.
  5. Zhang, H. Y.;  Wu, H. M.;  Jia, Y. H.;  Geng, L. J.;  Luo, Z. X.;  Fu, H. B.; Yao, J. N., An integrated instrument of DUV-IR photoionization mass spectrometry and spectroscopy for neutral clusters. Rev. Sci. Instrum. 2019, 90 (7), 073101.