金属团簇结构化学与反应性研究 金属团簇结构化学与反应性研究

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金属团簇结构化学与反应性研究

工作组成员：耿丽君、林世泉

 

在飞行时间质谱（TOF-MS）基础上，使用我国自主研发的深紫外（DUV）全固态激光器，结合宽调谐红外（IR）激光，能够同时而且准确地测试物质元素组成与化学结构，探究团簇物种的反应活性。

深紫外/红外离子化质谱光谱仪 DUV+IR

 

References

  1. Lijun Geng;  Chaonan Cui;  Baoqi Yin;  Hanyu Zhang;  Yuhan Jia; Zhixun Luo, Co12C12-——metallo-carbospherenes: a new class of magic clusters for hydrogen storage. Science Bulletin 2022.  Doi:https://doi.org/10.1016/j.scib.2022.10.004.
  2. Lijun Geng, Mouyi Weng, Cong-Qiao Xu, Hanyu Zhang, Chaonan Cui, Haiming Wu, Xin Chen, Mingyu Hu, Hai Lin, Zhen-Dong Sun, Xi Wang, Han-Shi Hu, Jun Li, Jiaxin Zheng, Zhixun Luo, Feng Pan, Jiannian Yao, Co13O8—Metalloxocubes: A new class of perovskite-like neutral clusters with cubic aromaticity, Natl. Sci. Rev. 2021, 8(1), nwaa201.
  3. Hanyu Zhang,# Haiming Wu,# Yuhan Jia, Baoqi Yin, Lijun Geng, Zhixun Luo and Klavs Hansen. The Reactivity of Cationic Vanadium Clusters with Water: Hy-drogen Release from Single H2O Molecule on Vn + (3 ≤ n ≤ 30), Commun. Chem., 2020, COMMSCHEM-20-0181C.
  4. Hanyu Zhang, Arthur C. Reber, Lijun Geng, Daniel Rabayda, Haiming Wu, Zhixun Luo*, Jiannian Yao, and Shiv N. Khanna*,Formation of Al+(C6H6)13: The Origin of Magic Number in Metal-benzene Clusters Determined by the Nature of the Core, CCS Chem. 2019, 1, 571-581.
  5. B. Yin, Q. Du, L. Geng, H. Zhang, Zhixun Luo, S. Zhou and J. Zhao, Anionic Copper Clusters Reacting with NO: An Open-Shell Superatom Cu18, J. Phys. Chem. Lett., 2020, 11, 5807-5814.
  6. B. Huang;  H. Zhang;  L. Geng; Z. Luo, An Open-Shell Superatom Cluster Ta10- with Enhanced Stability by United d-d pi Bonds and d-Orbital Superatomic States. J. Phys. Chem. Lett. 2022, 9711-9717.  Doi:10.1021/acs.jpclett.2c02410.
  7. Y. Jia, J. Li, M. Huang, L. Geng, H. Zhang, S. B. Cheng, Y. Yi, Z. Luo. Ladder oxygenation of group viii metal clusters and the formation of metalloxocubes M13O8+, J. Phys. Chem. Lett. 2022, 13, 733-739.
  8.  Yuhan Jia;  Xinlei Yu;  Hanyu Zhang;  Longjiu Cheng; Zhixun Luo, Tetrahedral Pt10– Cluster with Unique Beta Aromaticity and Superatomic Feature in Mimicking Methane. J. Phys. Chem.Lett. 2021, 5115-5122.
  9. Hanyu Zhang;  Mingzheng Zhang;  Yuhan Jia;  Lijun Geng;  Baoqi Yin;  Shunning Li;  Zhixun Luo; Feng Pan, Vanadium Cluster Neutrals Reacting with Water: Superatomic Features and Hydrogen Evolution in a Fishing Mode. J. Phys. Chem.Lett. 2021, 1593-1600.
  10. Hanyu Zhang;  Lijun Geng;  Yuhan Jia;  Xin Lei; Zhixun Luo*, A 45-degree ion-extraction photoelectron velocity map imaging apparatus coupled to the DUV-IR mass spectrometry and spectroscopy instrument. Int. J. Mass Spectrom. 2022.  Doi:10.1016/j.ijms.2022.116932.
  11. Zhang, H. Y.;  Wu, H. M.;  Jia, Y. H.;  Geng, L. J.;  Luo, Z. X.;  Fu, H. B.; Yao, J. N., An integrated instrument of DUV-IR photoionization mass spectrometry and spectroscopy for neutral clusters. Rev. Sci. Instrum. 2019, 90 (7), 073101.